Nubuhe buryo bwa reaction ya Tetrabutylammonium iyode?

Tetrabutylammonium iyodeni reagent ikoreshwa cyane muburyo butandukanye bwimiti.Imwe muma progaramu ishimishije kandi yizwe cyane ya TBAI nugukoresha muri synthesis ya azide.

Synonym:TBAI

Numero ya CAS:311-28-4

Ibyiza

Inzira ya molekulari

Imiti yimiti

C16H36IN

Uburemere bwa molekile

Uburemere bwa molekile

369.37g / mol

Ubushyuhe Ububiko

Ubushyuhe Ububiko

 

Ingingo yo gushonga

Ingingo yo gushonga

 

141-143 ℃

chem

Isuku

≥98%

Inyuma

Inyuma

ifu yera cyangwa ifu yera

Iyode ya Tetrabutylammonium, izwi kandi nka TBAI, ni reagent ikoreshwa cyane muburyo butandukanye bwimiti.Imwe muma progaramu ishimishije kandi yizwe cyane ya TBAI nugukoresha muri synthesis ya azide.Ariko ni ubuhe buryo bukubiye muri iki gisubizo, kandi ni gute TBAI yabigizemo uruhare?

 

Uburyo bwo gusubiza TBAI buragoye kandi burimo intambwe zingenzi.Muri rusange, iyi myitwarire ikubiyemo imiterere ya hypoiodite iva muri TBAI hamwe na co-reaction izwi nka TBHP.Iyi hypoiodite noneho ikora hamwe na karubone kugirango ikore intera hagati ya azide.Hanyuma, hypoiodite yongeye guhindurwa bundi bushya na okiside.

Intambwe yambere muburyo bwa reaction ikubiyemo kubyara hypoiodite kuva TBAI na TBHP.Iyi ni intambwe ikomeye kuko itangiza reaction itanga ubwoko bwa iyode bukenewe kugirango okiside ya karubone ikurikira.Hypoiodate irakora cyane kandi irashobora guteza imbere imiti myinshi itandukanye, harimo halogene na okiside.

Iyo hypoiodite imaze gushingwa, ikora hamwe na karubone ikora ibice.Hagati aho noneho irahagarikwa hakoreshejwe imide reagent, yongeramo atome ebyiri za azote kuri molekile kandi cyane cyane "igikora" kugirango irusheho kwitwara.Kuri ubu, TBAI yakoze intego zayo kandi ntigikenewe mubitekerezo.

 

Intambwe yanyuma muburyo bukubiyemo kuvugurura hypoiodite.Ibi bigerwaho na okiside ukoresheje co-reaction nka hydrogen peroxide.Kuvugurura hypoiodite nibyingenzi kuko bituma reaction ikomeza gusiganwa ku magare kandi ikabyara azide nyinshi.

Muri rusange, uburyo bwo gusubiza TBAI ni bwiza cyane kandi neza.Mugukora hypoiodite mumwanya no kuyikoresha muguhindura karuboni ya karubone, TBAI ifasha kubyara azide ubundi bigoye cyangwa bidashoboka guhuza.Waba uri chimiste ukora muri laboratoire yubushakashatsi cyangwa uruganda ushaka gukora ibikoresho bishya, TBAI ifite byinshi byo gutanga.Gerageza uyu munsi!


Igihe cyo kohereza: Jun-14-2023